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Facile Synthesis of a Rare Chlorosilylene–BH 3 Adduct
Author(s) -
Azhakar Ramachandran,
Tavčar Gašper,
Roesky Herbert W.,
Hey Jakob,
Stalke Dietmar
Publication year - 2011
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201001188
Subject(s) - adduct , chemistry , carbene , elemental analysis , mass spectrometry , nuclear magnetic resonance spectroscopy , crystal structure , medicinal chemistry , spectroscopy , infrared spectroscopy , crystallography , stereochemistry , organic chemistry , catalysis , physics , chromatography , quantum mechanics
The first stable chlorosilylene–BH 3 adduct was synthesized in the reaction of N‐heterocyclic carbene (NHC) stabilized dichlorosilylene either with equivalent amounts of LiBH 4 or with equivalent amounts of a BH 3 · THF solution. The chlorosilylene–BH 3 adduct was characterized by single‐crystal X‐ray structural analysis, NMR and IR spectroscopy, EI mass spectrometry, and elemental analysis.