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Synthesis and Structural Characterization of New Chiral (Biscarbene)platinum(II) Complexes
Author(s) -
Riederer Stephanie K. U.,
Bechlars Bettina,
Herrmann Wolfgang A.,
Kühn Fritz E.
Publication year - 2011
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201000939
Subject(s) - chemistry , hydrosilylation , platinum , catalysis , characterization (materials science) , polymer chemistry , stereochemistry , organic chemistry , nanotechnology , materials science
New chiral bis(triazolium) salts have been prepared in good yields. The corresponding mononuclear platinum(II) complexes [Pt{bis(NHC)}X 2 ] (X = Br, I) have been synthesized and spectroscopically characterized. One of the synthesized biscarbene complexes has also been characterised by X‐ray crystallography. These complexes are efficient catalyst precursors for the hydrosilylation of 1‐octene.