[{2,6‐(Me 2 NCH 2 ) 2 C 6 H 3 }Sn(μ‐OH)W(CO) 5 ] 2 : A Transition‐Metal‐Coordinated Organotin(II) Hydroxide

The synthesis of the intramolecularly coordinated pentacarbonyltungsten–organostannylene complexes {2,6‐(Me 2 NCH 2 ) 2 C 6 H 3 }Sn(H)W(CO) 5 ( 2 ) and [{2,6‐(Me 2 NCH 2 ) 2 C 6 H 3 }Sn(μ‐OH)W(CO) 5 ] 2 ( 3 ) and the solid‐state molecular structure of 3 , as determined by single‐crystal X‐ray diffraction analysis, are reported. Compound 3 is characterized by hydroxido bridges [Sn–O 2.068(5), 2.231(5) Å], an intramolecular N→Sn coordination bond [2.501(7) Å] and an intramolecular O–H ··· N hydrogen bond [O ··· N 2.715(8) Å].