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[{2,6‐(Me 2 NCH 2 ) 2 C 6 H 3 }Sn(μ‐OH)W(CO) 5 ] 2 : A Transition‐Metal‐Coordinated Organotin(II) Hydroxide
Author(s) -
Jambor Roman,
HerresPawlis Sonja,
Schürmann Markus,
Jurkschat Klaus
Publication year - 2011
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201000892
Subject(s) - chemistry , intramolecular force , crystallography , solid state , hydrogen bond , bond length , x ray crystallography , crystal structure , tin , stereochemistry , diffraction , molecule , organic chemistry , optics , physics
The synthesis of the intramolecularly coordinated pentacarbonyltungsten–organostannylene complexes {2,6‐(Me 2 NCH 2 ) 2 C 6 H 3 }Sn(H)W(CO) 5 ( 2 ) and [{2,6‐(Me 2 NCH 2 ) 2 C 6 H 3 }Sn(μ‐OH)W(CO) 5 ] 2 ( 3 ) and the solid‐state molecular structure of 3 , as determined by single‐crystal X‐ray diffraction analysis, are reported. Compound 3 is characterized by hydroxido bridges [Sn–O 2.068(5), 2.231(5) Å], an intramolecular N→Sn coordination bond [2.501(7) Å] and an intramolecular O–H ··· N hydrogen bond [O ··· N 2.715(8) Å].