Synthesis and Characterization of Unusual Oxidorhenium(V) Cores | Zendy

Nguyen Hung Huy | Zendy; Hazin Khatera | Zendy; Abram Ulrich | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Synthesis and Characterization of Unusual Oxidorhenium(V) Cores

Author(s) -

Nguyen Hung Huy,

Hazin Khatera,

Abram Ulrich

Publication year - 2011

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201000756

Subject(s) - chemistry , rhenium , sulfur , oxygen atom , stereochemistry , crystallography , atom (system on chip) , medicinal chemistry , inorganic chemistry , molecule , organic chemistry , computer science , embedded system

Reactions of (NBu 4 )[ReOCl 4 ] with N ‐( N ″, N ″‐dialkylaminothiocarbonyl)‐ N ′‐(2‐hydroxyphenyl)benzamidines (H 2 L 1 ) give complexes of the compositions [ReOCl(L 1 )] ( 1 ), cis ‐[ReO(L 1 )(OMe)] ( 2 ), or cis , cis ‐[{ReO(L 1 )} 2 O] ( 3 ) depending on the conditions applied. Compound 3 contains a bridging oxygen atom in the cis position to the terminal oxido ligands of both rhenium atoms. The analogous dimeric, sulfur‐bridged compound [{ReO(L 1 )} 2 S] ( 4 ) was obtained by the reaction of 1 with Na 2 S.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research