A Novel Water‐Soluble Hexanuclear Bismuth Oxido Cluster – Synthesis, Structure and Complexation with Polyacrylate | Zendy

Miersch Linda | Zendy; Rüffer Tobias | Zendy; Lang Heinrich | Zendy; Schulze Steffen | Zendy; Hietschold Michael | Zendy; Zahn Dirk | Zendy; Mehring Michael | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

A Novel Water‐Soluble Hexanuclear Bismuth Oxido Cluster – Synthesis, Structure and Complexation with Polyacrylate

Author(s) -

Miersch Linda,

Rüffer Tobias,

Lang Heinrich,

Schulze Steffen,

Hietschold Michael,

Zahn Dirk,

Mehring Michael

Publication year - 2010

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.201000753

Subject(s) - chemistry , triflic acid , bismuth , acetonitrile , monoclinic crystal system , aqueous solution , chloroform , inorganic chemistry , crystallization , medicinal chemistry , polymer chemistry , crystallography , crystal structure , organic chemistry , catalysis

The reaction of [Bi 6 O 4 (OH) 4 ](NO 3 ) 6 · H 2 O with triflic acid gave colorless single crystals of [Bi 6 O 4 (OH) 4 (OTf) 6 (CH 3 CN) 6 ] · 2CH 3 CN ( 1 ) upon crystallization from acetonitrile/chloroform. Compound 1 crystallizes in the monoclinic space group P 2 1 / n . The novel hexanuclear bismuth oxido cluster is highly soluble in water and polar organic solvents. A transparent and water‐soluble hybrid material was obtained by reaction of [Bi 6 O 4 (OH) 4 (OTf) 6 (CH 3 CN) 6 ] · 2CH 3 CN ( 1 ) with polyacrylate in aqueous solution. Molecular dynamics simulations were performed to study the complexation behavior of the [Bi 6 O 4+ x (OH) 4– x ] (6– x )+ cation with polyacrylate in solution.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research