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Polymorphism of Fluoroargentates(II): Facile Collapse of a Layered Network of α‐K 2 AgF 4 Due to the Insufficient Size of the Potassium Cation
Author(s) -
Kurzydłowski Dominik,
Derzsi Marianna,
Budzianowski Armand,
Jagličić Zvonko,
Koźmiński Wiktor,
Mazej Zoran,
Grochala Wojciech
Publication year - 2010
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.201000124
Subject(s) - chemistry , curie temperature , crystallography , ferromagnetism , ground state , band gap , fermi level , paramagnetism , condensed matter physics , crystal structure , atomic physics , physics , quantum mechanics , electron
We report the crystal structure and magnetic properties of a novel β polymorph of K 2 AgF 4 . β‐K 2 AgF 4 is paramagnetic above 20 K and exhibits a low Curie temperature ( θ < 5 K). Solid state DFT (GGA and GGA+U) calculations were performed to analyze the electronic and magnetic structure of β‐K 2 AgF 4 at 0 K/0 GPa, reproducing correctly the ferromagnetic (FM) semiconductor ground state with the band gap at the Fermi level of approximately 1.65 eV. Furthermore, we show that the novel β form is thermodynamically favoured over the previously reported two‐dimensional α form and can be formed either by slow spontaneous exothermic α to β phase transition occurring on heating or direct synthesis from KF and AgF 2 at 300 °C. The relative stability of the α and β phases is rationalized in terms of the size of the M + cation in the M 2 M′F 4 series (M = Na, K, Cs, M′ = Cu, Ag) and the mismatch between [MF] and [M′F 4/2 ] sublattices in the layered perovskite α form.