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Graphical Abstract: Eur. J. Inorg. Chem. 33/2009
Publication year - 2009
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200990092
Subject(s) - chemistry , lanthanide , vanadium , photoluminescence , cover (algebra) , molecule , metal , crystallography , luminescence , inorganic chemistry , ion , organic chemistry , optoelectronics , mechanical engineering , engineering , physics
The cover picture shows the porous mixed‐metal anionic MOF isolated from the self‐assembly of cyclic trinuclear vanadium‐based anionic units with aqua‐based lanthanide complexes. The structure contains a three‐dimensional channel system filled with water molecules and charge‐balancing cations, in which the most prominent channels run parallel to the c axis. The material containing V 4+ and Eu 3+ permits the fine‐tuning of the photoluminescence emission from white to purple‐blue. Details are discussed in the article by J. Rocha, F. A. Almeida Paz et al. on p. 4931 ff.