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Electro‐ and Photoinduced Formation and Transformation of Oxido‐Bridged Multinuclear Mn Complexes (Eur. J. Inorg. Chem. 14/2009)
Author(s) -
Collomb MarieNoëlle,
Deronzier Alain
Publication year - 2009
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200990035
Subject(s) - chemistry , manganese , ruthenium , stereochemistry , crystallography , polymer chemistry , photochemistry , catalysis , organic chemistry
The cover picture shows two examples of electroinduced formation and transformation of oxido‐bridged manganese complexes with polypyridyl ligands. The first example displays interconversion between mononuclear, dinuclear and tetranuclear cores accompanied by the concomitant formation (by oxidation) or breaking (by reduction) of μ‐oxido bridges. In the second example, core interconversion between μ‐oxido and μ‐acetato bridges in dinuclear manganese complexes is depicted. The background picture shows a schematic representation of the photoinduced formation of a dinuclear di‐μ‐oxido‐bridged manganese core from a mononuclear one in a superstructured complex of ruthenium and manganese. Details are presented in the Microreview by M.‐N. Collomb and A. Deronzier on p. 2025 ff. The authors thank Dr. Damien Jouvenot for his help in designing the cover picture.