Premium
Synthesis and Characterization of Task‐Specific Ionic Liquids Based on Peroxydisulfate and Their Application in Oxidation Reactions
Author(s) -
Shi Shenyi,
Kong Aiguo,
Zhao Xinhua,
Zhang Qiying,
Shan Yongkui
Publication year - 2010
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200901134
Subject(s) - chemistry , peroxydisulfate , ionic liquid , inorganic chemistry , thermal stability , solubility , elemental analysis , ionic bonding , ion , fourier transform infrared spectroscopy , viscosity , chemical engineering , organic chemistry , aqueous solution , catalysis , physics , quantum mechanics , engineering
Abstract Four new task‐specific ionic liquids based on the peroxydisulfate ion were synthesized by the ion exchange method and characterized by FTIR and 1 H NMR spectroscopy and elemental analysis. The physicochemical characteristics of these ionic liquids such as density, thermal stability, conductivity, viscosity, and solubility in common solvents have been investigated in detail. The experimental results testify that the ionic liquids prepared show excellent performance as both oxidant and medium in given oxidation reactions of alcohols and thiols under mild reaction conditions.