1,1′‐Diborylferrocenes from [2]Boraferrocenophanes by Boron–Boron Exchange | Zendy

Braunschweig Holger | Zendy; Grünewald Bernd | Zendy; Schwab Katrin | Zendy; Sigritz Rainer | Zendy

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1,1′‐Diborylferrocenes from [2]Boraferrocenophanes by Boron–Boron Exchange

Author(s) -

Braunschweig Holger,

Grünewald Bernd,

Schwab Katrin,

Sigritz Rainer

Publication year - 2009

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200900772

Subject(s) - chemistry , diborane , boron , borane , reactivity (psychology) , boranes , medicinal chemistry , inorganic chemistry , organic chemistry , catalysis , medicine , alternative medicine , pathology

The reactivity of [2]boraferrocenophane [(η 5 ‐C 5 H 4 )–BNMe 2 –BNMe 2 –(η 5 ‐C 5 H 4 )Fe] ( 3 ) with borane and diborane compounds was examined, resulting in the complete loss of the–BNMe 2 –BNMe 2 – bridge and the concomitant formation of 1,1′‐borylated ferrocenes. With this unprecedented reactivity pattern, an alternative access to this class of compounds is established.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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