Syntheses, Structures and Theoretical Investigations of [Li(thf) 4 ] 2 [Ti 2 Cu 8 S 4 (SPh) 10 ] and [Ti 2 Ag 6 S 6 Cl 2 (PPh i Pr 2 ) 6 ] | Zendy

Sommer Heino | Zendy; Drebov Nedko | Zendy; Eichhöfer Andreas | Zendy; Ahlrichs Reinhart | Zendy; Fenske Dieter | Zendy

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Syntheses, Structures and Theoretical Investigations of [Li(thf) 4 ] 2 [Ti 2 Cu 8 S 4 (SPh) 10 ] and [Ti 2 Ag 6 S 6 Cl 2 (PPh i Pr 2 ) 6 ]

Author(s) -

Sommer Heino,

Drebov Nedko,

Eichhöfer Andreas,

Ahlrichs Reinhart,

Fenske Dieter

Publication year - 2009

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200900581

Subject(s) - chemistry , titanium , crystal structure , crystallography , chlorine atom , cluster (spacecraft) , sulfur , chlorine , x ray crystallography , inorganic chemistry , stereochemistry , medicinal chemistry , diffraction , organic chemistry , physics , computer science , optics , programming language

The reaction of CuOAc (OAc = acetate) with TiCl 4 · 2thf and LiSPh in thf leads to the formation of tiny deep‐red crystals of [Li(thf) 4 ] 2 [Ti 2 Cu 8 S 4 (SPh) 10 ]. The silver/titanium cluster complex [Ti 2 Ag 6 S 6 Cl 2 (PPh i Pr 2 ) 6 ] was synthesized by the reaction of TiCl 4 · 2thf with AgPhCO 2 and S(SiMe 3 ) 2 in the presence of PPh i Pr 2 . The crystal structures of the compounds were determined by X‐ray analysis of single crystals. Additionally, theoretical investigations were performed to assign the proper chlorine/sulfur atomic positions and to rationalize the bonding situation in 1 and 2 . (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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