Molecular and Crystal Structures of Cp*M(S 2 N 2 ) (M = Co, Rh, Ir) and Related Compounds | Zendy

Matuska Vit | Zendy; Tersago Karla | Zendy; Kilian Petr | Zendy; Van Alsenoy Christian | Zendy; Blockhuys Frank | Zendy; Slawin Alexandra M. Z. | Zendy; Woollins J. Derek | Zendy

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Molecular and Crystal Structures of Cp*M(S 2 N 2 ) (M = Co, Rh, Ir) and Related Compounds

Author(s) -

Matuska Vit,

Tersago Karla,

Kilian Petr,

Van Alsenoy Christian,

Blockhuys Frank,

Slawin Alexandra M. Z.,

Woollins J. Derek

Publication year - 2009

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200900541

Subject(s) - chemistry , raman spectroscopy , microcrystalline , crystallography , infrared spectroscopy , crystal structure , crystal (programming language) , analytical chemistry (journal) , organic chemistry , programming language , physics , computer science , optics

Cp*Rh(S 2 N 2 ) was prepared as a microcrystalline solid by using [S 4 N 3 ]Cl in liquid ammonia or [ n Bu 2 Sn(S 2 N 2 )] 2 . It was characterised by NMR, IR and Raman spectroscopy andmass spectrometry. Low‐temperature crystal structures of Cp*Co(S 2 N 2 ) and Cp*Ir(S 2 N 2 ) were determined. The experimental characterisation of the Cp*M(S 2 N 2 ) complexes was complemented by calculated geometries and bond orders at the DFT/B1B95 level of theory. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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