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Molecular and Crystal Structures of Cp*M(S 2 N 2 ) (M = Co, Rh, Ir) and Related Compounds
Author(s) -
Matuska Vit,
Tersago Karla,
Kilian Petr,
Van Alsenoy Christian,
Blockhuys Frank,
Slawin Alexandra M. Z.,
Woollins J. Derek
Publication year - 2009
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200900541
Subject(s) - chemistry , raman spectroscopy , microcrystalline , crystallography , infrared spectroscopy , crystal structure , crystal (programming language) , analytical chemistry (journal) , organic chemistry , programming language , physics , computer science , optics
Cp*Rh(S 2 N 2 ) was prepared as a microcrystalline solid by using [S 4 N 3 ]Cl in liquid ammonia or [ n Bu 2 Sn(S 2 N 2 )] 2 . It was characterised by NMR, IR and Raman spectroscopy andmass spectrometry. Low‐temperature crystal structures of Cp*Co(S 2 N 2 ) and Cp*Ir(S 2 N 2 ) were determined. The experimental characterisation of the Cp*M(S 2 N 2 ) complexes was complemented by calculated geometries and bond orders at the DFT/B1B95 level of theory. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)