Molybdenum Carbonyl Complexes Bearing PN Ligands Based on 2‐Aminopyridine | Zendy

StandfestHauser Christina Maria | Zendy; Dazinger Georg | Zendy; Wiedermann Julia | Zendy; Mereiter Kurt | Zendy; Kirchner Karl | Zendy

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Molybdenum Carbonyl Complexes Bearing PN Ligands Based on 2‐Aminopyridine

Author(s) -

StandfestHauser Christina Maria,

Dazinger Georg,

Wiedermann Julia,

Mereiter Kurt,

Kirchner Karl

Publication year - 2009

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200900535

Subject(s) - chemistry , molybdenum , denticity , bromide , medicinal chemistry , oxidative addition , 2 aminopyridine , oxidative phosphorylation , nitrogen , stereochemistry , inorganic chemistry , crystallography , organic chemistry , crystal structure , catalysis , biochemistry

Molybdenum complexes of the general formula Mo(PN)(CO) 4 containing both achiral and chiral phosphorus‐nitrogen donor bidentate ligands based on 2‐aminopyridine were prepared and characterized by their NMR and IR spectra. The oxidative addition of allyl bromide to Mo(PN)(CO) 4 was studied with PN = N ‐(diisopropylphosphanyl)‐2‐aminopyridine (PN‐ i Pr). X‐ray structures of representative compounds were determined. The mechanism of the oxidative addition of allyl bromide to Mo(PN‐ i Pr)(CO) 4 was analyzed by DFT/B3LYP calculations. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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