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Spontaneous Reduction of High‐Spin Fe III Complexes Supported by Benzoic Hydrazide Derivative Ligands
Author(s) -
Bouslimani Nouri,
Clément Nicolas,
Toussaint Clément,
Hameury Sophie,
Turek Philippe,
Choua Sylvie,
Dagorne Samuel,
Martel David,
Welter Richard
Publication year - 2009
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200900382
Subject(s) - chemistry , electron paramagnetic resonance , hydrazide , derivative (finance) , crystallography , single crystal , spin (aerodynamics) , crystal (programming language) , medicinal chemistry , organic chemistry , nuclear magnetic resonance , programming language , physics , computer science , financial economics , engineering , economics , aerospace engineering
We report herein experimental evidence for the spontaneous reduction of new high‐spin iron(III) Fe III (L ( n ) ) 2 Cl, L complexes to new high‐spin iron(II) Fe II (HL ( n ) ) 2 Cl 2 mononuclear complexes. These processes were checked by EPR, cyclovoltammetric, and pseudo‐steady voltammetric studies. Crystal structures of three new complexes (one Fe III and two Fe II ) were obtained from RX single‐crystal diffraction.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)