Spontaneous Reduction of High‐Spin Fe III  Complexes Supported by Benzoic Hydrazide Derivative Ligands | Zendy

Bouslimani Nouri | Zendy; Clément Nicolas | Zendy; Toussaint Clément | Zendy; Hameury Sophie | Zendy; Turek Philippe | Zendy; Choua Sylvie | Zendy; Dagorne Samuel | Zendy; Martel David | Zendy; Welter Richard | Zendy

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Spontaneous Reduction of High‐Spin Fe III Complexes Supported by Benzoic Hydrazide Derivative Ligands

Author(s) -

Bouslimani Nouri,

Clément Nicolas,

Toussaint Clément,

Hameury Sophie,

Turek Philippe,

Choua Sylvie,

Dagorne Samuel,

Martel David,

Welter Richard

Publication year - 2009

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200900382

Subject(s) - chemistry , electron paramagnetic resonance , hydrazide , derivative (finance) , crystallography , single crystal , spin (aerodynamics) , crystal (programming language) , medicinal chemistry , organic chemistry , nuclear magnetic resonance , programming language , physics , computer science , financial economics , engineering , economics , aerospace engineering

We report herein experimental evidence for the spontaneous reduction of new high‐spin iron(III) Fe III (L ( n ) ) 2 Cl, L complexes to new high‐spin iron(II) Fe II (HL ( n ) ) 2 Cl 2 mononuclear complexes. These processes were checked by EPR, cyclovoltammetric, and pseudo‐steady voltammetric studies. Crystal structures of three new complexes (one Fe III and two Fe II ) were obtained from RX single‐crystal diffraction.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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