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Two New Imidazole‐Based Heteroscorpionate Ligands
Author(s) -
Fischer Nina V.,
Heinemann Frank W.,
Burzlaff Nicolai
Publication year - 2009
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200900374
Subject(s) - chemistry , rhenium , imidazole , ruthenium , methane , lithium (medication) , crystal structure , coordination complex , ethanol , medicinal chemistry , stereochemistry , crystallography , inorganic chemistry , organic chemistry , metal , catalysis , medicine , endocrinology
The syntheses of two novel imidazole‐based N , N , O and N , N , S ligands, 2,2‐bis( N ‐methylimidazol‐2‐yl)ethanol (Hbmie) and lithium bis( N ‐methylimidazol‐2‐yl)dithioacetate Li[bmidta], are described. The coordination properties of the two new ligands are studied by the synthesis of rhenium(I) and ruthenium(II) complexes. Single crystal X‐ray diffraction analyses of Hbmie, Li[bmidta] together with bis( N ‐methylimidazol‐2‐yl)methane (bmim) and [Re(bmie)(CO) 3 ] are provided, too.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)