Heteroleptic Amidinate Complexes of Heavy Group 15 Elements – Synthesis, X‐ray Crystal Structures and Theoretical Calculations | Zendy

Lyhs Benjamin | Zendy; Schulz Stephan | Zendy; Westphal Ulrich | Zendy; Bläser Dieter | Zendy; Boese Roland | Zendy; Bolte Michael | Zendy

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Heteroleptic Amidinate Complexes of Heavy Group 15 Elements – Synthesis, X‐ray Crystal Structures and Theoretical Calculations

Author(s) -

Lyhs Benjamin,

Schulz Stephan,

Westphal Ulrich,

Bläser Dieter,

Boese Roland,

Bolte Michael

Publication year - 2009

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200900233

Subject(s) - chemistry , crystallography , crystal structure , x ray , salt (chemistry) , single crystal , group (periodic table) , x ray crystallography , main group element , infrared spectroscopy , elemental analysis , nuclear magnetic resonance spectroscopy , diffraction , stereochemistry , inorganic chemistry , transition metal , organic chemistry , catalysis , physics , quantum mechanics , optics

Monosubstituted amidinate complexes [RC(NR′) 2 ]ECl 2 [E = Sb, R = t Bu, R′ = i Pr 1 , Cy 2 , 2,6‐ i Pr 2 C 6 H 3 (Dipp) 3 ; R = n Bu, R′ = i Pr 4 ; E = Bi, R = t Bu, R′ = i Pr 5 , Dipp 6 ] were prepared in high yields by salt elimination reactions of ECl 3 with Li amidinates. 1 – 6 were characterized by elemental analyses, NMR and IR spectroscopy and single‐crystal X‐ray diffraction. In addition, computational calculations were performed to clarify the different bonding modes in 1 and 5 . (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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