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Syntheses, Structures and Magnetic Properties of Dinuclear Copper(II)–Lanthanide(III) Complexes Bridged by 2‐Hydroxymethyl‐1‐methylimidazole (Eur. J. Inorg. Chem. 5/2008)
Author(s) -
Zhang WeiXiong,
Yang YangYi,
Zai ShaoBo,
Weng, Ng Seik,
Chen XiaoMing
Publication year - 2008
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200890006
Subject(s) - chemistry , lanthanide , antiferromagnetism , hydroxymethyl , crystallography , paramagnetism , copper , ligand (biochemistry) , ion , ferromagnetism , stereochemistry , inorganic chemistry , organic chemistry , biochemistry , physics , receptor , quantum mechanics , condensed matter physics
the cover picture shows a cupric metalloligand, formed by the mixed O‐ and N‐atom donor ligand 2‐hydroxymethyl‐1‐methylimidazole, that further ligates to lanthanide ions, which results in dinuclear CuLn complexes. With different lanthanide ions (Gd 3+ , La 3+ , and Sm 3+ ), the CuLn complexes have different structural features and exhibit ferromagnetic, paramagnetic and antiferromagnetic behavior, respectively. Details are discussed in the article by Y.‐Y. Yang, X.‐M. Chen et al. on p. 679 ff..