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The Inorganic–Organic Hybrid Compound {[Mn(trien)] 2 SnS 4 }·4H 2 O: Exhibiting a Hitherto Unknown Binding Mode of the [SnS 4 ] 4– Tetrahedron
Author(s) -
Pienack Nicole,
Näther Christian,
Bensch Wolfgang
Publication year - 2009
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200801093
Subject(s) - chemistry , octahedron , triethylenetetramine , crystallography , molecule , ion , manganese , crystal structure , stereochemistry , inorganic chemistry , organic chemistry
The compound {[Mn(C 6 H 18 N 4 )] 2 SnS 4 } · 4H 2 O (C 6 H 18 N 4 = triethylenetetramine) was obtained under solvothermal conditions. In the structure of the {[Mn(C 6 H 18 N 4 )] 2 SnS 4 } ∞ chain, two S atoms of the [SnS 4 ] 4– anion act in a hitherto never observed μ 3 bridging mode that connects the Mn 2 S 2 N 8 di‐octahedra. The Mn 2+ ions are octahedrally coordinated by four N and two S atoms, and two symmetry‐related octahedra share a common S–S edge. Three of the H 2 O molecules are joined into chains through H‐bonding interactions.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)