Expanding the Size of Organometallic Nanostructures: A Hexanuclear (Cymene)Ru Cylinder with a Length of More Than 3 nm | Zendy

Olivier Céline | Zendy; Scopelliti Rosario | Zendy; Severin Kay | Zendy

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Expanding the Size of Organometallic Nanostructures: A Hexanuclear (Cymene)Ru Cylinder with a Length of More Than 3 nm

Author(s) -

Olivier Céline,

Scopelliti Rosario,

Severin Kay

Publication year - 2009

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200801020

Subject(s) - chemistry , nanostructure , ruthenium , ligand (biochemistry) , p cymene , group 2 organometallic chemistry , crystallography , organometallic chemistry , nanotechnology , stereochemistry , crystal structure , molecule , organic chemistry , catalysis , receptor , biochemistry , materials science

Coordination cages based on organometallic half‐sandwich complexes are of interest, because they can display unique structures and host properties. This communication describes the synthesis and structure of a cylindrical nanostructure containing six ( p ‐cymene)Ru II fragments. The complex was obtained by reaction of [( p ‐cymene)RuCl 2 ] 2 with a novel C 3 ‐symmetrical ligand containing a triarylamine core and three dihydroxypyridine groups in its periphery. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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