Synthesis and Structure of an Unprecedented Linear Pentanuclear Bismuth(III) Zwitterionic Thiolate Complex | Zendy

Chen JinXiang | Zendy; Tang XiaoYan | Zendy; Ren ZhiGang | Zendy; Zhang Yong | Zendy; Lang JianPing | Zendy

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Synthesis and Structure of an Unprecedented Linear Pentanuclear Bismuth(III) Zwitterionic Thiolate Complex

Author(s) -

Chen JinXiang,

Tang XiaoYan,

Ren ZhiGang,

Zhang Yong,

Lang JianPing

Publication year - 2009

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200800969

Subject(s) - chemistry , bismuth , molar ratio , crystallography , crystal structure , crystal engineering , stereochemistry , inorganic chemistry , supramolecular chemistry , catalysis , organic chemistry

A unique pentanuclear bismuth(III) zwitterionic thiolate complex, [Bi 5 (Tab) 18 ](PF 6 ) 7 (NO 3 ) 8 ] · 6MeCN [ 1 ; Tab = 4‐(trimethylammonio)benzenethiolato], was obtained from the reaction of Bi(NO 3 ) 3 with TabHPF 6 in a 1:4 molar ratio in MeCN/MeOH in the presence of Et 3 N and structurally characterized. Single‐crystal X‐ray diffraction revealed that 1 consists of an unprecedented linear [Bi 5 (Tab) 18 ] 15+ cation, and both [PF 6 ] – and [NO 3 ] – anions in the crystal cooperatively work as anionic templates to form interesting anionic honeycomb‐like cavities for encapsulating the [Bi 5 (Tab) 18 ] 15+ cations.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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