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Structure and Magnetic Properties of Iron(II/III) Complexes with N 2 O 2 2– Coordinating Schiff Base Like Ligands
Author(s) -
Weber Birgit,
Jäger ErnstG.
Publication year - 2009
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200800891
Subject(s) - chemistry , schiff base , spin crossover , reactivity (psychology) , crystallography , base (topology) , magnetic susceptibility , biomolecule , inorganic chemistry , stereochemistry , polymer chemistry , medicine , mathematical analysis , biochemistry , alternative medicine , mathematics , pathology
An overview on the structure–reactivity relationship of iron(II/III) complexes with Schiff base like N 2 O 2 coordinating ligands is given. The high flexibility of the ligands results in a wide range of possible applications from model complexes for the reaction with small biomolecules such as nitric oxide to molecular switching materials either as a result of the occurrence of the spin‐crossover phenomenon or the spontaneous long‐range magnetic ordering. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)