Premium
N ‐Alkylation of Ammonioundecahydro‐ closo ‐dodecaborate(1–) for the Preparation of Anions for Ionic Liquids
Author(s) -
Justus Eugen,
Vöge Andrea,
Gabel Detlef
Publication year - 2008
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200800770
Subject(s) - chemistry , alkyl , alkylation , ionic liquid , ionic bonding , ion , medicinal chemistry , organic chemistry , inorganic chemistry , catalysis
Different N ‐alkylated derivatives of ammonioundecahydro‐ closo ‐dodecaborate(1–), [B 12 H 11 NH 3 ] – , were prepared. Strategies for the introduction of one alkyl chain or two equal alkyl chains and the trisubstitution by two different alkyl chains were developed. Several of the resulting salts have low melting points and are examples of a new class of ionic liquids.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)