Synthesis and Structure Determination of Selenium(IV) Cyanides | Zendy

Fritz Stefanie | Zendy; Lentz Dieter | Zendy; Szwak Małgorzata | Zendy

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Synthesis and Structure Determination of Selenium(IV) Cyanides

Author(s) -

Fritz Stefanie,

Lentz Dieter,

Szwak Małgorzata

Publication year - 2008

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200800712

Subject(s) - chemistry , selenium , tellurium , cyanide , dimethoxyethane , crystal structure , chalcogen , nmr spectra database , crystallography , medicinal chemistry , stereochemistry , inorganic chemistry , organic chemistry , spectral line , physics , electrode , astronomy , electrolyte

The reaction of SeF 4 with Me 3 SiCN did not result in thepreparation of the designated Se(CN) 4 but Se(CN)F 3 and Se(CN) 2 F 2 were obtained as first known selenium(IV)cyanide compounds and characterized by their NMR spectra. Se(CN) 2 F 2 was crystallized as 1,2‐dimethoxyethane solvate as well as the corresponding tellurium compound Te(CN) 2 F 2 with very similar structures. NMR spectroscopic data of some more miscellaneous tellurium cyanides and the crystal structures of solvates of Se(CN) 2 and oxygen‐bridged TeO(CN) 2 are presented. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

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