Premium
Recent Advances in the Design and Coordination Chemistry of Heteroscorpionate Ligands Bearing Stereogenic Centres
Author(s) -
Otero Antonio,
FernándezBaeza Juan,
LaraSánchez Agustín,
Tejeda Juan,
SánchezBarba Luis Fernando
Publication year - 2008
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200800710
Subject(s) - chemistry , stereocenter , denticity , coordination complex , stereochemistry , transition metal , medicinal chemistry , enantioselective synthesis , organic chemistry , catalysis , crystal structure , metal
This review concerns the recent studies carried out by our research group and others aimed at the design of heteroscorpionate ligands based on bis(pyrazol‐1‐yl)methane‐containing stereogenic centres. The capability of these systems to stabilize chiral complexes from early to late transition metals, through their behaviour as multidentate hybrid ligands, is also described.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)