Highly Luminescent Superparamagnetic Diterbium(III) Complex Based on the Bifunctionality of  p ‐ tert ‐Butylsulfonylcalix[4]arene | Zendy

Kajiwara Takashi | Zendy; Hasegawa Miki | Zendy; Ishii Ayumi | Zendy; Katagiri Kensuke | Zendy; Baatar Munkhtsetseg | Zendy; Takaishi Shinya | Zendy; Iki Nobuhiko | Zendy; Yamashita Masahiro | Zendy

Premium

Highly Luminescent Superparamagnetic Diterbium(III) Complex Based on the Bifunctionality of p ‐ tert ‐Butylsulfonylcalix[4]arene

Author(s) -

Kajiwara Takashi,

Hasegawa Miki,

Ishii Ayumi,

Katagiri Kensuke,

Baatar Munkhtsetseg,

Takaishi Shinya,

Iki Nobuhiko,

Yamashita Masahiro

Publication year - 2008

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200800706

Subject(s) - chemistry , superparamagnetism , chromophore , luminescence , quantum yield , yield (engineering) , relaxation (psychology) , antenna effect , ion , anisotropy , photochemistry , crystallography , optoelectronics , magnetization , optics , organic chemistry , fluorescence , magnetic field , psychology , social psychology , physics , materials science , quantum mechanics , metallurgy

A diterbium(III) complex was synthesized by using p‐tert ‐butylsulfonylcalix[4]arene, which adopts a 1,2‐alternate conformation, acts as a sensitive optical‐antenna chromophore for UV and near‐UV light and causes easy‐axis magnetic anisotropy in the Tb III ions. The complex showed efficient ff emission with a corrected quantum yield of ca. 85 % even at room temperature. In addition, it showed superparamagnetic behaviour due to slow magnetic relaxation at low temperatures.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research