Premium
Synthesis and Structural Characterization of Novel Neutral Hexacoordinate Silicon(IV) Complexes with SiS 2 O 2 N 2 Skeletons
Author(s) -
Metz Stefan,
Burschka Christian,
Tacke Reinhold
Publication year - 2008
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200800657
Subject(s) - hexacoordinate , chemistry , silicon , nuclear magnetic resonance spectroscopy , characterization (materials science) , spectroscopy , crystallography , solid state , solid state nuclear magnetic resonance , x ray crystallography , stereochemistry , diffraction , organic chemistry , nanotechnology , nuclear magnetic resonance , materials science , physics , quantum mechanics , optics
A series of novel hexacoordinate silicon(IV) complexes with two tridentate dianionic S,N,O ligands was synthesized, starting from Si(NCO) 4 . All the compounds synthesized were structurally characterized by single‐crystal X‐ray diffraction and/or solid‐state NMR spectroscopy. In addition, most of the compounds were characterized by solution NMR spectroscopy.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)