Synthesis and Structural Characterization of Novel Neutral Hexacoordinate Silicon(IV) Complexes with SiS 2 O 2 N 2  Skeletons | Zendy

Metz Stefan | Zendy; Burschka Christian | Zendy; Tacke Reinhold | Zendy

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Synthesis and Structural Characterization of Novel Neutral Hexacoordinate Silicon(IV) Complexes with SiS 2 O 2 N 2 Skeletons

Author(s) -

Metz Stefan,

Burschka Christian,

Tacke Reinhold

Publication year - 2008

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200800657

Subject(s) - hexacoordinate , chemistry , silicon , nuclear magnetic resonance spectroscopy , characterization (materials science) , spectroscopy , crystallography , solid state , solid state nuclear magnetic resonance , x ray crystallography , stereochemistry , diffraction , organic chemistry , nanotechnology , nuclear magnetic resonance , materials science , physics , quantum mechanics , optics

A series of novel hexacoordinate silicon(IV) complexes with two tridentate dianionic S,N,O ligands was synthesized, starting from Si(NCO) 4 . All the compounds synthesized were structurally characterized by single‐crystal X‐ray diffraction and/or solid‐state NMR spectroscopy. In addition, most of the compounds were characterized by solution NMR spectroscopy.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

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