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Rare Earth and Alkaline Earth Metal Complexes with Me 2 Si‐Bridged Cyclopentadienyl‐Imidazolin‐2‐Imine Ligands and Their Use as Constrained‐Geometry Hydroamination Catalysts
Author(s) -
Panda Tarun K.,
Hrib Cristian G.,
Jones Peter G.,
Jenter Jelena,
Roesky Peter W.,
Tamm Matthias
Publication year - 2008
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200800606
Subject(s) - hydroamination , chemistry , cyclopentadienyl complex , trimethylsilyl , imine , medicinal chemistry , ligand (biochemistry) , catalysis , metal , alkaline earth metal , lanthanide , polymer chemistry , organic chemistry , ion , biochemistry , receptor
The imidazolin‐2‐imino‐functionalized tetramethylcyclopentadiene, 3 ‐H, has been prepared by the reaction of two equivalents of 1,3‐diisopropyl‐4,5‐dimethylimidazolin‐2‐imine ( 1 ) with 5‐(chlorodimethylsilyl)‐1,2,3,4‐tetramethyl‐1,3‐cyclopentadiene ( 2 ). The reactions of 3 ‐H with the trimethylsilylmethyl (neosilyl) [Ln(CH 2 SiMe 3 ) 3 (THF) 2 ] (Ln = Sc, Y, Lu) complexes afford tetramethylsilane and the constrained‐geometry [(η 5 :η 1 ‐ 3 )Ln(CH 2 SiMe 3 ) 2 ] (Ln = Sc, 4a ; Ln = Y, 4b ; Ln = Lu, 4c ) complexes, whereas the analogousbis(trimethylsilyl)amido (HMDS) calcium complex, [(η 5 :η 1 ‐ 3 )Ca(HMDS)(THF)] ( 5 ), can be obtained from 3 ‐H and [Ca(HMDS) 2 (THF) 2 ] with loss of hexamethyldisilazane, (Me 3 Si) 2 NH. The molecular structures of 4a – 4c and 5 have been established by X‐ray diffraction analyses, which confirm in all cases the formation of complexes with a chelating Me 2 Si‐bridged cyclopentadienyl‐imidazolin‐2‐imine ligand. The presence of short Ln–N and Ca–N bonds is indicative of the strong electron‐donating capacity of the imidazolin‐2‐imino nitrogen atom, which is based on the ability of the imidazolium ring to effectively stabilize a positive charge. The rare earth metal complexes 4a – 4c can be used as efficient catalysts for the hydroamination/cyclization reaction of terminal aminoalkenes and aminoalkynes.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)