Tetrahedral Assembly with Lanthanides: Toward Discrete Polynuclear Complexes | Zendy

Hamacek Josef | Zendy; Bernardinelli Gérald | Zendy; Filinchuk Yaroslav | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Tetrahedral Assembly with Lanthanides: Toward Discrete Polynuclear Complexes

Author(s) -

Hamacek Josef,

Bernardinelli Gérald,

Filinchuk Yaroslav

Publication year - 2008

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200800455

Subject(s) - chemistry , lanthanide , tetrahedron , solid state , crystallography , nuclear magnetic resonance spectroscopy , ligand (biochemistry) , spectroscopy , self assembly , inorganic chemistry , stereochemistry , ion , organic chemistry , biochemistry , physics , receptor , quantum mechanics

We report on the preparation of discrete 3D tetrametallic edifices containing trivalent lanthanides (Eu–Lu). Their formation is thermodynamically controlled through self‐assembly with a new tripodal ligand L possessing short binding strands. X‐ray crystallography shows that four nine‐coordinate cations adopt a regular tetrahedral arrangement in the solid state. These remarkable, highly charged structures are maintained in solution, as demonstrated by NMR spectroscopy, ESI‐MS and spectrophotometry.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research