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A Ferromagnetically Coupled Diiron(III) Complex with a m ‐Phenylenediamine‐Based Ligand
Author(s) -
Biswas Biplab,
SalunkeGawali Sunita,
Weyhermüller Thomas,
Bachler Vinzenz,
Bill Eckhard,
Chaudhuri Phalguni
Publication year - 2008
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200800255
Subject(s) - chemistry , schiff base , ligand (biochemistry) , crystallography , stereochemistry , receptor , biochemistry
The Schiff base ligand H 2 L, N , N′ ‐bis(3,5‐di‐ tert ‐butylsalicylidene)‐1,3‐diaminobenzene yields a diferric complex, [L 2 Fe III 2 (NO 3 ) 2 ] ( 1 ), in which the d 5 high‐spin iron(III) centers are ferromagnetically coupled through the spin polarization mechanism. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
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