Synthesis of Enantiopure Ruthenium Tricarbonyl Complexes of a Bicyclic Cyclopentadienone Derivative | Zendy

Kim Minsoo | Zendy; Lee Jun Won | Zendy; Lee Jae Eun | Zendy; Kang Jahyo | Zendy

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Synthesis of Enantiopure Ruthenium Tricarbonyl Complexes of a Bicyclic Cyclopentadienone Derivative

Author(s) -

Kim Minsoo,

Lee Jun Won,

Lee Jae Eun,

Kang Jahyo

Publication year - 2008

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200800174

Subject(s) - enantiopure drug , chemistry , ruthenium , menthone , bicyclic molecule , derivative (finance) , alcohol , malonate , organic chemistry , stereochemistry , enantioselective synthesis , menthol , catalysis , financial economics , economics

(–)‐Menthone was converted stereoselectively into 3‐menthylpropargyl alcohol 8 in several steps and subsequently converted into enantiopure cyclopentadienone ruthenium carbonyl complexes. In the malonate cases, ruthenacycle 15 was also formed during the cyclization reaction. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

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