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Synthesis of Enantiopure Ruthenium Tricarbonyl Complexes of a Bicyclic Cyclopentadienone Derivative
Author(s) -
Kim Minsoo,
Lee Jun Won,
Lee Jae Eun,
Kang Jahyo
Publication year - 2008
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200800174
Subject(s) - enantiopure drug , chemistry , ruthenium , menthone , bicyclic molecule , derivative (finance) , alcohol , malonate , organic chemistry , stereochemistry , enantioselective synthesis , menthol , catalysis , financial economics , economics
(–)‐Menthone was converted stereoselectively into 3‐menthylpropargyl alcohol 8 in several steps and subsequently converted into enantiopure cyclopentadienone ruthenium carbonyl complexes. In the malonate cases, ruthenacycle 15 was also formed during the cyclization reaction. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)