Silylene and Germylene Intermediates in the Reactions of Silole and Germole Dianions with  N , N′ ‐Di‐ tert ‐butylethylenediimine | Zendy

Toulokhonova Irina S. | Zendy; Timokhin Vitaly I. | Zendy; Bunck David N. | Zendy; Guzei Ilia | Zendy; West Robert | Zendy; Müller Thomas | Zendy

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Silylene and Germylene Intermediates in the Reactions of Silole and Germole Dianions with N , N′ ‐Di‐ tert ‐butylethylenediimine

Author(s) -

Toulokhonova Irina S.,

Timokhin Vitaly I.,

Bunck David N.,

Guzei Ilia,

West Robert,

Müller Thomas

Publication year - 2008

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200800083

Subject(s) - silylene , chemistry , dilithium , adduct , reaction mechanism , medicinal chemistry , photochemistry , organic chemistry , catalysis , ion , silicon , deprotonation

Spiro‐diazasilole (germole) adducts were observed in reactions of dilithium salts of silole and germole dianions with N , N ′‐di‐ tert ‐butylethylenediimine in THF at room temperature. A proposed mechanism of the reaction includes metallation of N , N ′‐di‐ tert ‐butylethylenediimine and the formation of an intermediate silylene or germylene. This reaction mechanism was supported by experimental data and theoretical calculations. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

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