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Mechanistic Studies on the Activation of NO by Iron and Cobalt Complexes (Eur. J. Inorg. Chem. 6/2007)
Author(s) -
Franke Alicia,
Roncaroli Federico,
van Eldik Rudi
Publication year - 2007
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200790008
Subject(s) - chemistry , cobalt , metal , diamagnetism , volume (thermodynamics) , stereochemistry , computational chemistry , crystallography , inorganic chemistry , thermodynamics , organic chemistry , physics , quantum mechanics , magnetic field
The cover picture shows how mechanistic insight into the activation of NO by biological and model metal complexes can be gained through volume profile analysis. The presented volume profile describes the binding of NO to the high‐spin, five‐coordinate Fe III centre in cytochrome P450 in the presence of camphor to form a low‐spin (diamagnetic), six‐coordinate Fe II –NO + product. Details are presented in the Microreview by R. van Eldik et al. on p. 773 ff.