Synthesis and Characterization of the New Tetrameric Magnesium Imide Compound [(thf)MgNSiPh 3 ] 4 | Zendy

Fuchs Alexander | Zendy; Kaifer Elisabeth | Zendy; Himmel HansJörg | Zendy

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Synthesis and Characterization of the New Tetrameric Magnesium Imide Compound [(thf)MgNSiPh 3 ] 4

Author(s) -

Fuchs Alexander,

Kaifer Elisabeth,

Himmel HansJörg

Publication year - 2008

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200701155

Subject(s) - chemistry , imide , magnesium , amine gas treating , aryl , medicinal chemistry , nitrogen , stereochemistry , polymer chemistry , organic chemistry , alkyl

Reaction between di‐ n ‐butylmagnesium and the primary amine H 2 NSiPh 3 affords the tetrameric magnesium imide [(thf)MgNSiPh 3 ] 4 , representing the first example of a structurally characterized magnesium imide in which the group attached to the nitrogen is not aryl. The four Mg and N atoms are arranged in the form of a distorted heterocubane unit. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

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