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Synthesis and Characterization of the New Tetrameric Magnesium Imide Compound [(thf)MgNSiPh 3 ] 4
Author(s) -
Fuchs Alexander,
Kaifer Elisabeth,
Himmel HansJörg
Publication year - 2008
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200701155
Subject(s) - chemistry , imide , magnesium , amine gas treating , aryl , medicinal chemistry , nitrogen , stereochemistry , polymer chemistry , organic chemistry , alkyl
Reaction between di‐ n ‐butylmagnesium and the primary amine H 2 NSiPh 3 affords the tetrameric magnesium imide [(thf)MgNSiPh 3 ] 4 , representing the first example of a structurally characterized magnesium imide in which the group attached to the nitrogen is not aryl. The four Mg and N atoms are arranged in the form of a distorted heterocubane unit. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)