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A Versatile and Low‐Toxicity Route for the Production of Electroceramic Oxide Nanopowders
Author(s) -
Morata Alejandro,
Chesnaud Anthony,
Tarancón Alberto,
Estradé Sonia,
Peiró Francesca,
Morante JoanRamon,
Dezanneau Guilhem
Publication year - 2008
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200701026
Subject(s) - calcination , crystallite , thermogravimetry , chemistry , oxide , aqueous solution , chemical engineering , non blocking i/o , soft chemistry , nuclear chemistry , inorganic chemistry , crystallography , organic chemistry , catalysis , engineering
An alternative route to acrylamide gel polymerisation is presented for the preparation of oxide nanopowders. Within this method, cations first dissolved in an aqueous solution are subsequently trapped inside a 3D chelating gel beforefast‐drying, which leads to a stable precursor. In this study, we have prepared compositions corresponding to a wide range of state‐of‐the‐art fuel cells materials such as: Zr 0.85 Y 0.15 O 1.875 , Ce 0.9 Gd 0.1 O 1.95 , Nd 1.95 NiO 4+ x , GdBaCo 2 O 5+ x , Ba 0.5 Sr 0.5 Co 0.8 Fe 0.2 O 3– x and La 0.75 Sr 0.25 Cr 0.5 Mn 0.5 O 3 . Thermogravimetry and differential thermal analysis studies have been performed to determine the best calcination conditions. After calcination, the resulting powders have been characterised by X‐ray diffraction, FEG‐scanning electron microscopy and TEM. The synthesised powders are of nanometric crystallite size and have flake‐like aggregates; pure phases are obtained at low temperature. We made this method more attractive by using a nontoxic polymer and a nonexplosive initiator. This route allows the easy preparation of more than tens of grams of nanometric powders in one batch. Finally, since this process is largely independent of the formula of the compound, it can easily be extended to other kinds of oxides such as ferroelectric, CMR (colossal magnetoresistance) or gas sensor compounds.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)