Organization of the Ru 2 Na Moiety of a Phenazine Ligand Into a New Coordination Network Promoted by ClO 4 –Aromatic‐π Interactions | Zendy

Banerjee Priyabrata | Zendy; Jana Atish Dipankar | Zendy; Mostafa Golam | Zendy; Goswami Sreebrata | Zendy

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Organization of the Ru 2 Na Moiety of a Phenazine Ligand Into a New Coordination Network Promoted by ClO 4 –Aromatic‐π Interactions

Author(s) -

Banerjee Priyabrata,

Jana Atish Dipankar,

Mostafa Golam,

Goswami Sreebrata

Publication year - 2008

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200700929

Subject(s) - chemistry , supramolecular chemistry , moiety , phenazine , intermolecular force , ligand (biochemistry) , ruthenium , hydrogen bond , crystal structure , crystallography , bipyridine , coordination complex , stereochemistry , medicinal chemistry , molecule , catalysis , organic chemistry , metal , biochemistry , receptor

A unique supramolecular network of the trimetallic building unit [(bpy) 2 Ru(LO)Na(LO)Ru(bpy) 2 ](ClO 4 ) 5 · 3H 2 O {bpy = 2,2′‐bipyridine, LO = 7‐methoxy‐5‐(4‐methoxyphenyl)‐2,3‐bis(4‐methoxyphenylimino)‐3,5‐dihydro‐2 H ‐phenazin‐1‐one} is described. Crystal growth is driven by several synergistic intermolecular interactions including ClO 4 –π, π–π, C–H ··· π and hydrogen bonding. Optical properties of the supramolecule are modified due to aggregation. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

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