Premium
Organization of the Ru 2 Na Moiety of a Phenazine Ligand Into a New Coordination Network Promoted by ClO 4 –Aromatic‐π Interactions
Author(s) -
Banerjee Priyabrata,
Jana Atish Dipankar,
Mostafa Golam,
Goswami Sreebrata
Publication year - 2008
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200700929
Subject(s) - chemistry , supramolecular chemistry , moiety , phenazine , intermolecular force , ligand (biochemistry) , ruthenium , hydrogen bond , crystal structure , crystallography , bipyridine , coordination complex , stereochemistry , medicinal chemistry , molecule , catalysis , organic chemistry , metal , biochemistry , receptor
A unique supramolecular network of the trimetallic building unit [(bpy) 2 Ru(LO)Na(LO)Ru(bpy) 2 ](ClO 4 ) 5 · 3H 2 O {bpy = 2,2′‐bipyridine, LO = 7‐methoxy‐5‐(4‐methoxyphenyl)‐2,3‐bis(4‐methoxyphenylimino)‐3,5‐dihydro‐2 H ‐phenazin‐1‐one} is described. Crystal growth is driven by several synergistic intermolecular interactions including ClO 4 –π, π–π, C–H ··· π and hydrogen bonding. Optical properties of the supramolecule are modified due to aggregation. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)