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Transition‐Metal‐Free Boron–Carbon Bond Activation: Insertion of an NNP Fragment into a Boron–Carbon Bond
Author(s) -
Kowalewski Markus,
Krumm Burkhard,
Mayer Peter,
Schulz Axel,
Villinger Alexander
Publication year - 2007
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200700895
Subject(s) - chemistry , boron , reactivity (psychology) , fluorine , lewis acids and bases , transition metal , carbon fibers , medicinal chemistry , metal , stereochemistry , phosphorus , main group element , polymer chemistry , organic chemistry , catalysis , medicine , materials science , alternative medicine , pathology , composite number , composite material
The influence and reactivity of fluorine‐containing Lewis acids such as neat BF 3 , BF 3 · OEt 2 , and B(C 6 F 5 ) 3 on Me 3 SiCl elimination in (Me 3 Si) 2 N–N(SiMe 3 )–PCl 2 was investigated. The reaction with B(C 6 F 5 ) 3 resulted in the formation of a novel diazadiphosphetidine with a phosphorus(III) atom attached to a pentafluorophenyl group, which can be regarded as a formal NNP fragment insertion into a B–C bond.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)