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Reductive Nitrosation of Peptides Ligated to High‐Valent Metal Cations
Author(s) -
Shamir Dror,
Zilbermann Israel,
Maimon Eric,
Gellerman Gary,
Cohen Haim,
Meyerstein Dan
Publication year - 2007
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200700867
Subject(s) - chemistry , nitrosation , metal , peptide , combinatorial chemistry , radical , medicinal chemistry , stereochemistry , organic chemistry , biochemistry
NO reacts with M III –(glycylglycylglycine), M = Fe; Ni and Cu, to form the terminal N ‐nitrosated peptide complex. This reaction proceeds by a radical mechanism. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
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