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Coordination Polymers Constructed from [Mn(N)(CN) 4 ] 2– : Synthesis, Structures, and Magnetic Properties
Author(s) -
Guo JunFang,
Yeung WaiFun,
Gao Song,
Lee GeneHsiang,
Peng ShieMing,
Lam Michael HonWah,
Lau TaiChu
Publication year - 2008
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200700807
Subject(s) - cyclen , chemistry , crystallography , paramagnetism , manganese , polymer , chain (unit) , metal , stereochemistry , organic chemistry , condensed matter physics , physics , astronomy
The dimetallic complexes [{Ni(cyclen)}{Mn(N)(CN) 4 } · CH 3 OH] n (cyclen = 1,4,7,10‐tetraazacyclododecane) ( 1 ), [{Cu(cyclen)}{Mn(N)(CN) 4 }] n ( 2 ), and [{Mn(5,5′‐Me 2 salen)} 2 {Mn(N)(CN) 4 } · CH 3 OH] n [5,5′‐Me 2 salen = N , N′ ‐bis(5,5′‐dimethylsalicylidene)‐ o ‐ethylenediimine] ( 3 ) have been synthesized and structurally characterized. Compounds 1 and 2 have one‐dimensional chain structures, while compound 3 has a two‐dimensional sheet‐like network structure. Magnetic studies of 1 and 3 show that there is no significant magnetic coupling between the paramagnetic metal centers. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
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