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Complexation of 2,6‐Bis(3‐pyrazolyl)pyridine–Bis(thiocyanato)iron(II) with a Bridging 4,4′‐Bipyridine: A New Example of a Dinuclear Spin Crossover Complex
Author(s) -
Fedaoui Dalila,
Bouhadja Yacine,
Kaiba Abdellah,
Guionneau Philippe,
Létard JeanFrançois,
Rosa Patrick
Publication year - 2008
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200700708
Subject(s) - chemistry , spin crossover , pyridine , bridging (networking) , bipyridine , coordination complex , crystallography , 4,4' bipyridine , antiferromagnetism , stereochemistry , molecule , medicinal chemistry , crystal structure , organic chemistry , hydrogen bond , condensed matter physics , metal , computer network , computer science , physics
Investigation of the coordination behavior of 2,6‐bis(3‐pyrazolyl)pyridine–bis(thiocyanato)iron(II) towards bridging ligands led to the discovery of a novel dinuclear complex showing spin‐crossover. Chemical and structural characterization and a first report of physical properties are presented.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)