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The First Heterohexametallic Transition‐Metal Complex
Author(s) -
Packheiser Rico,
Lang Heinrich
Publication year - 2007
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200700617
Subject(s) - chemistry , transition metal , metal , bridging ligand , ligand (biochemistry) , stereochemistry , crystallography , organic chemistry , catalysis , biochemistry , receptor
The synthesis and characterisation of a first heteromultimetallic transition metal complex with six different metal atoms (Fe, Ru, Re, Au, Cu and Ti), connected through carbon‐rich bridging units, are reported. Complex {1‐[(η 2 ‐dppf)(η 5 ‐C 5 H 5 )RuC≡C]‐3‐[(bipy*)(CO) 3 ReC≡C]‐5‐[PPh 2 AuC≡C‐bipy({[Ti](μ‐σ,π‐C≡CSiMe 3 ) 2 }Cu)]C 6 H 3 }PF 6 is accessible in a consecutive reaction sequence by applying building blocks from a ligand and coordination complex library. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)