Effect of Deprotonation of a Benzimidazolyl Ligand on the Redox Potential and the Structures of Mononuclear Ruthenium(II) Complexes | Zendy

Sun Hongfei | Zendy; Wang Mei | Zendy; Jin Kun | Zendy; Ma Chengbing | Zendy; Zhang Rong | Zendy; Sun Licheng | Zendy

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Effect of Deprotonation of a Benzimidazolyl Ligand on the Redox Potential and the Structures of Mononuclear Ruthenium(II) Complexes

Author(s) -

Sun Hongfei,

Wang Mei,

Jin Kun,

Ma Chengbing,

Zhang Rong,

Sun Licheng

Publication year - 2007

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200700549

Subject(s) - deprotonation , chemistry , ruthenium , ligand (biochemistry) , protonation , redox , stereochemistry , photochemistry , medicinal chemistry , inorganic chemistry , organic chemistry , catalysis , receptor , biochemistry , ion

A monoruthenium(II) complex of the benzimidazolyl ligand and its deprotonated counterpart were prepared and structurally characterized. The reversible protonation/deprotonation process of the ancillary ligand switches the redox potential of the ruthenium(II) core from 0.69 to 0.26 V vs. Ag/AgNO 3 . (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

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