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Controlled Chemical Reduction of Uranyl Salts into UX 4 (MeCN) 4 (X = Cl, Br, I) with Me 3 SiX Reagents
Author(s) -
Berthet JeanClaude,
Siffredi Gérald,
Thuéry Pierre,
Ephritikhine Michel
Publication year - 2007
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200700272
Subject(s) - chemistry , uranyl , acetonitrile , uranium , reagent , actinide , inorganic chemistry , medicinal chemistry , organic chemistry , ion , materials science , metallurgy
UO 2 I 2 (thf) 3 or UO 2 (OTf) 2 are easily reduced by Me 3 SiX (X = Cl, Br, I) in acetonitrile into the tetravalent UX 4 (MeCN) 4 complexes, which are useful precursors in uranium chemistry. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)