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Alternating and Non‐Alternating Pd‐Catalysed Co‐ and Terpolymerisation of Carbon Monoxide and Alkenes
Author(s) -
García Suárez Eduardo J.,
Godard Cyril,
Ruiz Aurora,
Claver Carmen
Publication year - 2007
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200700024
Subject(s) - chemistry , carbon monoxide , palladium , styrene , catalysis , monomer , monoxide , carbon fibers , polymer chemistry , organic chemistry , polymer , copolymer , composite number , materials science , composite material
The co‐ and terpolymerisation of carbon monoxide and alkenes are usually catalysed by palladium complexes, and the properties of the produced polyketones can be finely tuned by an appropriate choice of catalyst and olefinic monomer. After a general overview of the topic, selected recent advances in this field are described. The use of palladium systems containing modified diphosphane and/or new phosphorus‐based ligands, and the results obtained using a series of modular N and S ligands, including chiral ligands, in CO/styrene co‐ and terpolymerisations are reported. The use of new P‐O ligands in non‐alternating CO/ethene copolymerisation is also described. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)