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Chiral Half‐Sandwich Ruthenium(II) Complexes as Catalysts in 1,3‐Dipolar Cycloaddition Reactions of Nitrones with Methacrolein (Eur. J. Inorg. Chem. 16/2006)
Author(s) -
Carmona Daniel,
Lamata M. Pilar,
Viguri Fernando,
Ferrer Joaquina,
García Néstor,
Lahoz Fernando J.,
Martín M. Luisa,
Oro Luis A.
Publication year - 2006
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200690032
Subject(s) - methacrolein , chemistry , nitrone , cycloaddition , ruthenium , oxazoline , catalysis , enantioselective synthesis , ligand (biochemistry) , isopropyl , medicinal chemistry , stereochemistry , polymer chemistry , photochemistry , organic chemistry , polymer , polymerization , biochemistry , receptor , methacrylic acid
The cover picture shows the structure of a chiral half‐sandwich ruthenium(II) complex with the (4 S )‐2‐[2‐(diphenylphosphanyl)phenyl]‐4‐isopropyl‐1,3‐oxazoline ligand that catalyzes the asymmetric 1,3‐dipolar cycloaddition reaction of nitrones with methacrolein. Catalyst precursors as well as dipolarophile or nitrone‐containing intermediates have been isolated and spectroscopically and/or crystallographically characterized. Details are discussed in the article by D. Carmona, M. P. Lamata, L. A. Oro et al. on p. 3155 ff.