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Coordination Dependence of Magnetic Properties within a Family of Related [Fe II 2 ] Complexes of a Triazine‐Based Ligand (Eur. J. Inorg. Chem. 7/2006)
Author(s) -
Quesada Manuel,
de Hoog Paul,
Gamez Patrick,
Roubeau Olivier,
Aromí Guillem,
Donnadieu Bruno,
Massera Chiara,
Lutz Martin,
Spek Anthony L.,
Reedijk Jan
Publication year - 2006
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200690014
Subject(s) - chemistry , triazine , antiferromagnetism , ligand (biochemistry) , ferromagnetism , crystallography , spin crossover , crystal structure , coupling (piping) , inductive coupling , magnetic susceptibility , condensed matter physics , polymer chemistry , physics , metallurgy , materials science , biochemistry , receptor , quantum mechanics
The cover picture shows the crystal structures of three related iron( II ) complexes obtained with a triazine‐based polypyridyl ligand, where minor structural changes result in very disparate magnetic properties, ranging from antiferromagnetic exchange through spin crossover to ferromagnetic coupling. These are clearly illustrated by the characteristic plots of the corresponding magnetic behaviours. The background map of Europe symbolizes the European collaboration responsible for the studies reported by P. Gamez, O. Roubeau, et al. on p. 1353 ff.