Coupling Reactions of an Allenylcarbene Complex with Alkynes and Styrene | Zendy

Wen Ting Bin | Zendy; Hung Wai Yiu | Zendy; Sung Herman H.Y. | Zendy; Zhou Zhongyuan | Zendy; Williams Ian D. | Zendy; Jia Guochen | Zendy

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Coupling Reactions of an Allenylcarbene Complex with Alkynes and Styrene

Author(s) -

Wen Ting Bin,

Hung Wai Yiu,

Sung Herman H.Y.,

Zhou Zhongyuan,

Williams Ian D.,

Jia Guochen

Publication year - 2007

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200601251

Subject(s) - chemistry , fulvene , styrene , medicinal chemistry , coupling (piping) , coupling reaction , reactivity (psychology) , organic chemistry , catalysis , mechanical engineering , engineering , copolymer , polymer , medicine , alternative medicine , pathology

The allenylcarbene complex [OsCl 2 {=CPh(η 2 ‐CH=C=CHPh)}(PPh 3 ) 2 ] undergoes coupling reactions with HC≡CSiMe 3 and PhC≡CC≡CPh to produce the fulvene complexes [OsCl 2 {η 6 ‐C 5 H 2 (Ph)(SiMe 3 )(=CHPh)}(PPh 3 )] and [OsCl 2 {η 6 ‐C 5 H(Ph) 2 (C≡CPh)(=CHPh)}(PPh 3 )], respectively. A similar coupling reaction also occurs between [OsCl 2 {=CPh(η 2 ‐CH=C=CHPh)}(PPh 3 ) 2 ] and styrene.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

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