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Polymer‐Supported Dioxido‐Mo VI Complexes as Truly Functional Molybdenum Oxotransferase Model Systems
Author(s) -
Heinze Katja,
Fischer Andreas
Publication year - 2007
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200601120
Subject(s) - chemistry , molybdenum , homogeneous , polymer , electron paramagnetic resonance , model system , polymer chemistry , inorganic chemistry , organic chemistry , computational chemistry , nuclear magnetic resonance , thermodynamics , physics
A truly functional model system for molybdenum oxotransferases provides evidence for all biologically realistic intermediates, namely mononuclear Mo VI , Mo V and Mo IV species. Dinucleation to EPR‐silent [Mo V 2 O 3 ] species prevailing in homogeneous solution is suppressed by immobilising the active species to a polymeric support by two‐point attachment.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)