Polymer‐Supported Dioxido‐Mo VI  Complexes as Truly Functional Molybdenum Oxotransferase Model Systems | Zendy

Heinze Katja | Zendy; Fischer Andreas | Zendy

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Polymer‐Supported Dioxido‐Mo VI Complexes as Truly Functional Molybdenum Oxotransferase Model Systems

Author(s) -

Heinze Katja,

Fischer Andreas

Publication year - 2007

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200601120

Subject(s) - chemistry , molybdenum , homogeneous , polymer , electron paramagnetic resonance , model system , polymer chemistry , inorganic chemistry , organic chemistry , computational chemistry , nuclear magnetic resonance , thermodynamics , physics

A truly functional model system for molybdenum oxotransferases provides evidence for all biologically realistic intermediates, namely mononuclear Mo VI , Mo V and Mo IV species. Dinucleation to EPR‐silent [Mo V 2 O 3 ] species prevailing in homogeneous solution is suppressed by immobilising the active species to a polymeric support by two‐point attachment.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

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