A Two‐Dimensional, Hydrogen‐Bond‐Cross‐Linked Molybdenum(VI) Network Polymer with Catalytic Activity | Zendy

Luan Yi | Zendy; Wang Ge | Zendy; Luck Rudy L. | Zendy; Yang Mu | Zendy

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A Two‐Dimensional, Hydrogen‐Bond‐Cross‐Linked Molybdenum(VI) Network Polymer with Catalytic Activity

Author(s) -

Luan Yi,

Wang Ge,

Luck Rudy L.,

Yang Mu

Publication year - 2007

Publication title -

european journal of inorganic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 1434-1948

DOI - 10.1002/ejic.200601054

Subject(s) - chemistry , catalysis , molybdenum , propane , hydrogen bond , hydrogen , polymer , inorganic chemistry , polymer chemistry , molecule , medicinal chemistry , organic chemistry

The new hybrid inorganic–organic polymer [MoO 2 Cl 2 (H 2 O) 2 ] · (H 2 dipy‐pra)Cl 2 ( 1 ), where dipy‐pra = 1,3‐bis(4‐pyridyl)propane, has been synthesized and crystallographically characterized. MoO 2 Cl 2 (H 2 O) 2 and the [H 2 dipy‐pra] 2+ cation are cross‐linked by Mo–H 2 O ··· Cl and H 2 dipy‐pra ··· Cl hydrogen bonds to form a two‐dimensional layer structure. Complex 1 is an efficient catalyst, with H 2 O 2 as the oxygen‐source oxidant and NaHCO 3 as the cocatalyst, in the epoxidation of olefinic compounds under ambient conditions.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

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