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A Two‐Dimensional, Hydrogen‐Bond‐Cross‐Linked Molybdenum(VI) Network Polymer with Catalytic Activity
Author(s) -
Luan Yi,
Wang Ge,
Luck Rudy L.,
Yang Mu
Publication year - 2007
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200601054
Subject(s) - chemistry , catalysis , molybdenum , propane , hydrogen bond , hydrogen , polymer , inorganic chemistry , polymer chemistry , molecule , medicinal chemistry , organic chemistry
The new hybrid inorganic–organic polymer [MoO 2 Cl 2 (H 2 O) 2 ] · (H 2 dipy‐pra)Cl 2 ( 1 ), where dipy‐pra = 1,3‐bis(4‐pyridyl)propane, has been synthesized and crystallographically characterized. MoO 2 Cl 2 (H 2 O) 2 and the [H 2 dipy‐pra] 2+ cation are cross‐linked by Mo–H 2 O ··· Cl and H 2 dipy‐pra ··· Cl hydrogen bonds to form a two‐dimensional layer structure. Complex 1 is an efficient catalyst, with H 2 O 2 as the oxygen‐source oxidant and NaHCO 3 as the cocatalyst, in the epoxidation of olefinic compounds under ambient conditions.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)