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New Type of Photoluminescent Iridium Complex: Novel Synthetic Route for Cationic trans ‐Bis(2‐phenylpyridinato)iridium(III) Complex
Author(s) -
Chin Chong Shik,
Eum MinSik,
Kim Song yi,
Kim Choongil,
Kang Sung Kwon
Publication year - 2006
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200600888
Subject(s) - iridium , chemistry , cationic polymerization , photoluminescence , polymer chemistry , combinatorial chemistry , stereochemistry , catalysis , organic chemistry , optoelectronics , physics
A new type of iridium(III) complex [ trans ‐Ir(ppy) 2 (PPh 3 ) 2 ] + ( 1 ) has been prepared by a novel synthetic method and its structural and photoluminescent characteristics have been compared with those of the cis analogue, [ cis ‐Ir(ppy) 2 (PPh 3 )(P(OPh) 3 )] + ( 2 ) which has also been newly prepared in this study. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)