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Activation of Aromatic, Aliphatic, and Olefinic Carbon–Fluorine Bonds Using Cp* 2 HfH 2
Author(s) -
Rieth Ryan D.,
Brennessel William W.,
Jones William D.
Publication year - 2007
Publication title -
european journal of inorganic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 1434-1948
DOI - 10.1002/ejic.200600802
Subject(s) - chemistry , reactivity (psychology) , hydride , fluorine , medicinal chemistry , carbon fibers , organic chemistry , hydrogen , medicine , materials science , alternative medicine , pathology , composite number , composite material
Abstract The hafnium hydride Cp* 2 HfH 2 is reacted with a series of fluorocarbons to examine the scope of C–F bond activation. Aromatic, vinylic, and aliphatic C–F bonds all show some degree of reactivity, and possible mechanisms are discussed. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)